The engineering team is continuing to work on adding support for multiple accounts on desktop clients. We will first launch support for 1 work/school account and 1 personal account so users can enjoy Teams for work and personal side-by-side. Windows and MacOS. Support for multiple work accounts is still being worked on and will come at a later date.
You can track status via the roadmap here: https://www.microsoft.com/microsoft-365/roadmap?searchterms=68845.
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Our employees work with two accounts, but they cannot switch to teams without logging out and logging in. Sometimes there are also disruptions. The same account change function should be implemented here as in the mobile app.