The engineering team is continuing to work on adding support for multiple accounts on desktop clients. We will first launch support for 1 work/school account and 1 personal account so users can enjoy Teams for work and personal side-by-side. Windows and MacOS. Support for multiple work accounts is still being worked on and will come at a later date.
You can track status via the roadmap here: https://www.microsoft.com/microsoft-365/roadmap?searchterms=68845.
Thank you for this feedback! Fortunately, this feature already exists. Just drag and drop items in the order you desire.
Let me know if you have any more questions on this!